Di Gi Charat (a.k.a. Dejiko) - along with Petit Charat (a.k.a. Puchiko) and Gema - travels to Earth as part of her training to become a full-fledged princess. They crash on a small town in Japan, where they meet the Omocha brothers (who spend most of their time thinking how cute Puchiko is) and Mr. & Mrs. Ankoro (an elderly couple that makes Japanese sweets).
EP72 - Digiko mo Usamimi Hoshii nyo 
